Where is this song in the film Tangled?

This, according to the official Tangled movie soundtrack, is called 'When Will My Life Begin (Reprise 1)' and comes after the first one and before the second reprise, when she leaves the tower with Flynn Rider. In the movie and CD, reprise 1 comes just before 'Mother Knows Best', so just before Rapunzel asks Mother Gothel to leave the tower.